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A18613 2-Chlorocyclohexanone, 97%, stab. with calcium carbonate/magnesium oxide

CAS Number
822-87-7
Synonyms

Stock No. Size Price ($) Quantity Availability
A18613-09 10g 31.40
A18613-18 50g 105.00
A18613-30 250g 406.00
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2-Chlorocyclohexanone, 97%, stab. with calcium carbonate/magnesium oxide

MDL
MFCD00001626
EINECS
212-505-5

Chemical Properties

Formula
C6H9ClO
Formula Weight
132.59
Melting point
22-24°
Boiling Point
82-83°/10mm
Flash Point
82°(180°F)
Density
1.161
Refractive Index
1.4840
Storage & Sensitivity
Store at -20°C. Store under Argon.
Solubility
Insoluble in water.

Applications

2-Chlorocyclohexanone, is an intermediate in the synthesis of variety of pharmaceutical compounds. It is also an intermediate in the synthesis of 1-Chloro-2-methylenecyclohexane .

Notes

Store away from oxidizing agents and heat. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep refrigerated at -20°C.

Literature References

C. David. Gutsche. Ring Enlargements. I. The Ring Enlargement of 2-Chlorocyclohexanone and 2-Phenylcyclohexanone.J. Am. Chem. Soc.,1949,71(10), 3513-3517.

R. L. Huang. The Reaction Of 2-Chlorocyclohexanone With Grignard Reagents And The Rearrangement Of The Resulting Chlorohydrins.J. Org. Chem.,1954,19(8), 1363-1369.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H317-H319-H335

Combustible liquid. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P272-P280-P302+P352-P304+P340-P305+P351+P338-P312-P333+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
774100
Harmonized Tariff Code
2914.79
TSCA
Yes
RTECS
GW1225000

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