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1514-87-0 - Methyl chlorodifluoroacetate, 98% - Chlorodifluoroacetic acid methyl ester - A18623 - Alfa Aesar

A18623 Methyl chlorodifluoroacetate, 98%

CAS Number
1514-87-0
Synonyms
Chlorodifluoroacetic acid methyl ester

Size Price ($) Quantity Availability
10g 26.06
50g 97.94
250g 383.20
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Methyl chlorodifluoroacetate, 98%

MDL
MFCD00000775
EINECS
216-154-9

Chemical Properties

Formula
ClCF2CO2CH3
Formula Weight
144.50
Boiling Point
79-81°
Flash Point
19°(66°F)
Density
1.371
Refractive Index
1.3500
Sensitivity
Moisture Sensitive

Literature References

Convenient trifluoromethylating agent. In combination with CuI, KF and DMF, trifluoromethylation of aryl and vinyl halides is achieved via the generation of trifluoromethylcopper: Tetrahedron Lett., 32, 7689 (1991); J. Fluorine Chem., 55, 225 (1992). Similarly, nitroaryl chlorides undergo substitution to give the trifluoromethyl derivatives in high yield: J. Fluorine Chem., 66, 167 (1994).

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GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1756072
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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