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A18623 Methyl chlorodifluoroacetate, 98%

CAS Number
1514-87-0
Synonyms
Chlorodifluoroacetic acid methyl ester

Stock No. Size Price ($) Quantity Availability
A18623-09 10g 26.00
A18623-18 50g 113.00
A18623-30 250g 479.00
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Methyl chlorodifluoroacetate, 98%

MDL
MFCD00000775
EINECS
216-154-9

Chemical Properties

Formula
ClCF2CO2CH3
Formula Weight
144.50
Boiling Point
79-81°
Flash Point
19°(66°F)
Density
1.371
Refractive Index
1.3500
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.

Literature References

Convenient trifluoromethylating agent. In combination with CuI, KF and DMF, trifluoromethylation of aryl and vinyl halides is achieved via the generation of trifluoromethylcopper: Tetrahedron Lett., 32, 7689 (1991); J. Fluorine Chem., 55, 225 (1992). Similarly, nitroaryl chlorides undergo substitution to give the trifluoromethyl derivatives in high yield: J. Fluorine Chem., 66, 167 (1994).

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GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H335

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1756072
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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