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1477-50-5 - Indole-2-carboxylic acid, 98+% - A18690 - Alfa Aesar

A18690 Indole-2-carboxylic acid, 98+%

CAS Number
1477-50-5
Synonyms

Size Price ($) Quantity Availability
10g 56.80
50g 184.00
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Indole-2-carboxylic acid, 98+%

MDL
MFCD00005611
EINECS
216-030-4

Chemical Properties

Formula
C9H7NO2
Formula Weight
161.16
Melting point
ca 205° dec.
Solubility
Soluble in clear yellow solution 5% in ethanol, dimethyl sulfoxide and methanol.

Applications

Reactant for total synthesis of (±)-dibromophakellin and analogs, synthesis of the pyrrolizidine alkaloid (±)-trachelanthamidine, stereo selective preparation of renieramycin G analogs, preparation of spirooxoindolepyrrolidines via reduction of indole-2-carboxylic acid followed by oxidation, condensation, reduction, amidation and Kharasch radical cyclization, Pd-catalyzed cyclization and N,N?-(pentane)diylbis[indolecarboxamide] and N,N?-[phenylenebis(methylene)]bis[indolecarboxamide] derivatives.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Nicole M Hewlett; and Jetze J Tepe.Total synthesis of the natural product (±)-dibromophakellin and analogues. Organic Letters, 2011, 13 (17), 4550-4553.

Stefano Nicolai et. al. A palladium-catalyzed aminoalkynylation strategy towards bicyclic heterocycles: synthesis of (±)-trachelanthamidine. Angewandte Chemie. International edition in English, 2011, 50(20), 4680-4683.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
124132
Harmonized Tariff Code
2933.99
TSCA
No
RTECS
NK7882812

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