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A18766 N,N-Dimethylbenzamide, 98+%

CAS Number
611-74-5
Synonyms

Stock No. Size Price ($) Quantity Availability
A18766-14 25g 35.40
A18766-22 100g 92.50
A18766-36 500g 391.00
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N,N-Dimethylbenzamide, 98+%

MDL
MFCD00008320
EINECS
210-279-2

Chemical Properties

Formula
C9H11NO
Formula Weight
149.19
Melting point
42-45°
Boiling Point
132-133°/15mm
Flash Point
>110°(230°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Reagent for deoxygenation of secondary alcohols.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Ji Young Kim et. al. Hydrotropic polymer micelles as versatile vehicles for delivery of poorly water-soluble drugs. Journal of Controlled Release, 2011, 152 (1), 13-20.

Yokoo K, et al. Reactions of ethyl-and phenyllanthanide s complexes with n, n-dimethylbenzamide and benzaldehyde. Polyhedron , 1983, 2(10), 1101-02.

Has been used as an acylating agent for alkynyl boranes: Chem. Lett., 35 (1983).Similarly, reacts with Grignard reagents in ether, to give phenyl ketones in good yields: Synthesis, 228 (1984). For o-lithiation of N,N-dialkylbenzamides, see N,N-Diethyl­benzamide, L08427 and N,N-Diisopropyl­benzamide, B22918.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
774955
Harmonized Tariff Code
2924.29
TSCA
Yes
RTECS
CV4500000

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