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3938-96-3 - Ethyl methoxyacetate, 98% - Methoxyacetic acid ethyl ester - A18770 - Alfa Aesar

A18770 Ethyl methoxyacetate, 98%

CAS Number
3938-96-3
Synonyms
Methoxyacetic acid ethyl ester

Size Price ($) Quantity Availability
10g 46.03
50g 136.80
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Ethyl methoxyacetate, 98%

MDL
MFCD00009176
EINECS
223-521-7

Chemical Properties

Formula
CH3OCH2CO2CH2CH3
Formula Weight
118.13
Boiling Point
44-46°/9mm
Flash Point
46°(115°F)
Density
1.00
Refractive Index
1.401
Solubility
Slightly soluble in water.

Applications

Ethyl methoxyacetate was used as acyl donor during the preparation of enantiomers of several phenylethylamines, as acylation reagent for the aminolysis of 1-phenylethanamine and used in an industrial, lipase-catalyzed kinetic resolution of primary amine.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Lourdes Muñoz; Anna M Rodriguez; Gloria Rosell; M Pilar Bosch; Angel Guerrero. Enzymatic enantiomeric resolution of phenylethylamines structurally related to amphetamine. Organic & Biomolecular Chemistry, 2011, 9 (23), 8171-8177.

Maria Cammenberg; Karl Hult; Seongsoon Park. Molecular basis for the enhanced lipase-catalyzed N-acylation of 1-phenylethanamine with methoxyacetate. ChemBioChem, 2006, 7(11), 1745-1749.

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1744761
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2918.99
TSCA
No

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