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3401-47-6 - 1-Bromo-2-methoxynaphthalene, 97% - A18926 - Alfa Aesar

A18926 1-Bromo-2-methoxynaphthalene, 97%

CAS Number
3401-47-6
Synonyms

Size Price ($) Quantity Availability
5g 32.66
25g 120.92
100g 531.75
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1-Bromo-2-methoxynaphthalene, 97%

MDL
MFCD00055374
EINECS
222-272-1

Chemical Properties

Formula
C11H9BrO
Formula Weight
237.10
Melting point
79-80°
Solubility
Slightly soluble in water.

Applications

1-Bromo-2-methoxy-naphthalene is a useful synthetic intermediate. It is used as a reagent to synthesize a catalyst for highly enantioselective aziridination of styrene derivatives. It can also be used to prepare biaryls or biheterocycles by palladium-catalyzed Ullmann coupling.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

M. Carmen Carreno; Jose L. Garcia Ruano; Gema Sanz; Miguel A. Toledo; Antonio Urbano. N-Bromosuccinimide in Acetonitrile: A Mild and Regiospecific Nuclear Brominating Reagent for Methoxybenzenes and Naphthalenes. J. Org. Chem., 1995, 60 (16), 5328-5331.

George Majetich; Rodgers Hicks; and Steven Reister. Electrophilic Aromatic Bromination Using Bromodimethylsulfonium Bromide Generated in Situ. J. Org. Chem, 1997, 62(13), 4321-4326.

Other References

Beilstein
2045600
Harmonized Tariff Code
2909.30
TSCA
No

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