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124-02-7 - Diallylamine, 98% - A18950 - Alfa Aesar

A18950 Diallylamine, 98%

CAS Number
124-02-7
Synonyms

Size Price ($) Quantity Availability
100ml 27.09
500ml 46.40
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Diallylamine, 98%

MDL
MFCD00008642
EINECS
204-671-2

Chemical Properties

Formula
(CH2=CHCH2)2NH
Formula Weight
97.16
Melting point
-88°
Boiling Point
111-112°
Flash Point
7°(44°F)
Density
0.789
Refractive Index
1.4405
Sensitivity
Air Sensitive
Solubility
Soluble in ethanol and ether. Moderately soluble in water.

Applications

Diallylamine is used as an intermediate for ion exchange resins, pharmaceuticals, water soluble polymers, rubber chemicals, polymerization initiators and cross-linking agents.

Notes

Air Sensitive. store away from water/moisture and air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Florence Garro-Helion; Ahmed Merzouk; Francois Guibe. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines. J. Org. Chem., 1993, 58 (22), 6109-6113.

Susumu Harada; and Masamichi Katayama. The cyclo-copolymerization of diallyl compound and sulfur dioxide. I. Diallylamine hydrochloride and sulfur dioxide. Journal of Bacteriology, 1966, 90(1), 177-186.

Pd catalyzed coupling with aryl or heteroaryl halides followed by cleavage with methanesulfonic acid or BF3 etherate in the presence of Pd on carbon, provides a mild route to aryl or heteroaryl amines in which the diallylamine behaves as an ammonia equivalent: Tetrahedron Lett., 39, 1313 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H311-H330-H302-H314-H318

Highly flammable liquid and vapour. Toxic in contact with skin. Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,2971
Beilstein
773718
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2921.19
TSCA
Yes
RTECS
UC6650000

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