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2-Aminothiophenol was used in the synthesis of 1,5-benzothiazepines derivatives by reacting with 1,3-diphenylpropenone derivatives and using aluminosilicate solid catalysts. It was also used in the synthesis of benzothiazole2 and 3-(benzothiazol-2-yl)coumarin derivatives. The ternary complexes of copper (II) with salicylidene-2-aminothiophenol (L) and glycine, alanine, valine and histidene amino acids.
Maria J Climent et. al. Solid catalysts for multistep reactions: one-pot synthesis of 2,3-dihydro-1,5-benzothiazepines with solid acid and base catalysts. Chemsuschem Chemistry And Sustainability, Energy & Materials. 2014, 7(4), 1177-1185.
Valfredo Azevedo Lemos, , Patrícia Xavier Baliza. Amberlite XAD-2 functionalized with 2-aminothiophenol as a new sorbent for on-line preconcentration of cadmium and copper. Talanta. 2005, 67 (3), 564-570.
Reacts with carboxylic acid chlorides in N-methylpyrrolidinone to give 2-substituted benzothiazoles: Synth. Commun., 20, 3379 (1990), and with substituted benzonitriles in the presence of sodium hydride to give 2-arylbenzothiazoles: Heterocycles, 38, 1001 (1994).
Hazard Statements: H227-H301-H314-H318-H317-H373
Combustible liquid. Toxic if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P210u-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.