Synthesis of p-terphenyls by dou- ble Suzuki reactions of methyl 2,5-dibromobenzoate. The synthesis of liquid crystal crown ether was commenced with methyl 2,5-dibromobenzoate (27) that was coupled with 4-(decyloxy)phenylboronic acid in a subsequent Pd0-catalyzed Suzuki reaction.
Rene Plehnert,; Jörg Andreas Schröter,; Carsten Tschierske. Selective Cationic Binding at the Air-Water Interface by Thin Films of Rigid Amphiphiles Bearing Laterally Attached Crown Ether Moieties. Langmuir. 1988, 14 (18), 5245-5249.
P. Paoli; M. Altamura; P. Dapporto; A. Guidi; N. J. S. Harmat; L. Jierry and P. Rossi. Tricyclic systems as potential bio-scaffolds: testing their relative flexibility. Acta Cryst. 2007, A63, s206-s207.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.