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4-Bromophenylacetone is used to prepare biphenyl-4-yl-acetone by reacting with phenylboronic acid using cesium fluoride as a reagent and palladium phosphine complex as a catalyst.
Weidmann, V.; Ploog, J.; Kliewer, S.; Schaffrath, M.; Maison, W. Variants of the Prins Cyclization for the Synthesis of Terpenoid Spiroethers and Oxabicyclo[3.3.1]Nonane Derivatives. J. Org. Chem. 2014, 79 (21), 10123-10131.
Sasnouski, G.; Lapanik, V.; Bezborodov, V.; Dabrowski, R.; Dziaduszek, J. Synthesis of fluoro substituted quaterphenyl liquid crystals. Phase Transitions 2014, 87 (8), 783-789.