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6117-80-2 - cis-2-Butene-1,4-diol, 96%, remainder trans-isomer - 1,4-Dihydroxy-cis-2-butene - A19182 - Alfa Aesar

A19182 cis-2-Butene-1,4-diol, 96%, remainder trans-isomer

CAS Number
6117-80-2
Synonyms
1,4-Dihydroxy-cis-2-butene

Size Price ($) Quantity Availability
250g 39.40
1000g 93.40
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cis-2-Butene-1,4-diol, 96%, remainder trans-isomer

MDL
MFCD00002924
EINECS
228-085-1

Chemical Properties

Formula
C4H8O2
Formula Weight
88.11
Melting point
6-8°
Boiling Point
131-132°/12mm
Flash Point
127°(260°F)
Density
1.070
Refractive Index
1.4780
Solubility
Soluble in water.

Applications

cis-2-Butene-1, 4-diol is used as a probe for studying isomerization versus hydrogenation and hydrogenolysis reactions. (DPCB-OMe) efficiently catalyzes cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds to give 2-vinyl-2,3-dihydrofurans in good to high yields. Grubbs's cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Chun-xiu Pan,; Xiu-zhu Xu,; Hong-mei He,; Xiao-jun Cai,; Xue-jun Zhang. Separation and identification of cis and trans isomers of 2-butene-1,4-diol and lafutidine by HPLC and LC-MS.. Journal of Zhejiang University (Science B). 2005, 6 (1), 74-78 .

Hiromi Murakami,; Yukio Matsui,; Fumiyuki Ozawa,; Masaaki Yoshifuji. Cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds catalyzed by a diphosphinidenecyclobutene-coordinated palladium complex . Journal of Organometallic Chemistry. 2006, 691 (14) ,3151-3156.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1679241
Harmonized Tariff Code
2905.49
TSCA
No
RTECS
EM4970000

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