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4360-63-8 - 2-Bromomethyl-1,3-dioxolane, 97% - Bromoacetaldehyde ethylene acetal - A19312 - Alfa Aesar

A19312 2-Bromomethyl-1,3-dioxolane, 97%

CAS Number
4360-63-8
Synonyms
Bromoacetaldehyde ethylene acetal

Size Price ($) Quantity Availability
25g 58.20
100g 168.00
500g 901.00
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2-Bromomethyl-1,3-dioxolane, 97%

MDL
MFCD00003214
EINECS
224-443-6

Chemical Properties

Formula
C4H7BrO2
Formula Weight
167.01
Boiling Point
175°
Flash Point
62°(145°F)
Density
1.628
Refractive Index
1.4820
Sensitivity
Moisture Sensitive
Solubility
Immiscible with water.

Applications

2-Bromomethyl-1,3-dioxolane is used in the preparation of alfa, beta-unsaturated aldehyde and 1, 4-two aldehyde monoacetals synthesis of monomers.

Notes

Moisture sensitive. Incompatible with strong oxidizing agents, strong acids and strong bases.

Literature References

McInroy, G. R.; Raiber, E. A.; Balasubramanian, S. Chemical biology of genomic DNA: minimizing PCR bias. Chem. Commun. 2014, 50, 12047-12049.

Gao, F.; Deng, X. J.; Tang, Y.; Tang, J. P.; Yang, J.; Zhang, Y. M. A simple and efficient copper oxide-catalyzed Barbier-Grignard reaction of unactivated aryl or alkyl bromides with ester. Tetrahedron Lett. 2014, 55 (4), 880-883.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210u-P261-P280a-P280a-P305+P351+P338-P304+P340-P312a-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
103309
Harmonized Tariff Code
2932.99
TSCA
Yes

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