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A19312 2-Bromomethyl-1,3-dioxolane, 97%

CAS Number
4360-63-8
Synonyms
Bromoacetaldehyde ethylene acetal

Stock No. Size Price ($) Quantity Availability
A19312-14 25g 58.60
A19312-22 100g 169.00
A19312-36 500g 844.00
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2-Bromomethyl-1,3-dioxolane, 97%

MDL
MFCD00003214
EINECS
224-443-6

Chemical Properties

Formula
C4H7BrO2
Formula Weight
167.01
Boiling Point
175°
Flash Point
62°(145°F)
Density
1.628
Refractive Index
1.4820
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Immiscible with water.

Applications

2-Bromomethyl-1,3-dioxolane is used in the preparation of alfa, beta-unsaturated aldehyde and 1, 4-two aldehyde monoacetals synthesis of monomers.

Notes

Moisture sensitive. Incompatible with strong oxidizing agents, strong acids and strong bases.

Literature References

McInroy, G. R.; Raiber, E. A.; Balasubramanian, S. Chemical biology of genomic DNA: minimizing PCR bias. Chem. Commun. 2014, 50, 12047-12049.

Gao, F.; Deng, X. J.; Tang, Y.; Tang, J. P.; Yang, J.; Zhang, Y. M. A simple and efficient copper oxide-catalyzed Barbier-Grignard reaction of unactivated aryl or alkyl bromides with ester. Tetrahedron Lett. 2014, 55 (4), 880-883.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
103309
Harmonized Tariff Code
2932.99
TSCA
Yes

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