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771-60-8 - Pentafluoroaniline, 98+% - A19348 - Alfa Aesar

A19348 Pentafluoroaniline, 98+%

CAS Number
771-60-8
Synonyms

Size Price ($) Quantity Availability
5g 24.30
25g 81.25
100g 216.54
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Pentafluoroaniline, 98+%

MDL
MFCD00007643
EINECS
212-234-2

Chemical Properties

Formula
C6H2F5N
Formula Weight
183.08
Melting point
34-37°
Boiling Point
156-157°
Flash Point
73°(163°F)
Density
1.744
Solubility
Soluble in toluene, and organic solvents. Insoluble in water.

Applications

2,3,4,5,6-Pentafluoroaniline finds it uses in the preparation of pentafluorophenylammonium triflate, an efficient catalyst for esterification and thioesterification. It is also used in the synthesis of various titanium complexes having two anionic [N, O-] bidentate salicylaldiminato ligands.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Funatomi T, et al. Pentafluorophenylammonium triflate (PFPAT): an efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation.Green Chem.2006,8(12), 1022-1027.

Parssinen A, et al. Bis (salicylaldiminato) titanium complexes containing bulky imine substituents: Synthesis, characterization and ethene polymerization studies.Eur. J. Inorg. Chem. 2005,2005(11), 2100-2109.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1819387
Harmonized Tariff Code
2921.42
TSCA
Yes
RTECS
BY7920000

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