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5111-65-9 - 2-Bromo-6-methoxynaphthalene, 98% - 2-Methoxy-6-bromonaphthalene - A19450 - Alfa Aesar

A19450 2-Bromo-6-methoxynaphthalene, 98%

CAS Number
5111-65-9
Synonyms
2-Methoxy-6-bromonaphthalene

Size Price ($) Quantity Availability
10g 50.88
50g 179.10
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2-Bromo-6-methoxynaphthalene, 98%

MDL
MFCD00004062
EINECS
225-837-0

Chemical Properties

Formula
C11H9BrO
Formula Weight
237.10
Melting point
105-110°
Boiling Point
160-164°/3mm
Solubility
Soluble in DMSO. Insoluble in water.

Applications

2-Bromo-6-methoxynaphthalene is used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Howard Alper.; Nathalie Hamel. Asymmetric synthesis of acids by the palladium-catalyzed hydrocarboxylation of olefins in the presence of (R)-(-)- or (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate. J. Am. Chem. Soc. 1990, 112, (7), 2803-2804.

Stephen W. Wright.; David L. Hageman.; Lester D. McClure. Fluoride-Mediated Boronic Acid Coupling Reactions. J. Org. Chem. 1994, 59, (20), 6095-6097.

Undergoes highly efficient, phosphine-free Suzuki coupling reactions with arylboronic acids in water, catalyzed by Pd(II) acetate in the presence of TBAB and potassium carbonate: J. Org. Chem., 62, 7170 (1997).

Other References

Beilstein
2043874
Harmonized Tariff Code
2909.30
TSCA
No

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