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A19480 2,6-Dimethylphenyl isothiocyanate, 98%

CAS Number
19241-16-8
Synonyms

Stock No. Size Price ($) Quantity Availability
A19480-06 5g 51.30
A19480-14 25g 162.00
A19480-22 100g 502.00
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2,6-Dimethylphenyl isothiocyanate, 98%

MDL
MFCD00038715
EINECS
242-906-0

Chemical Properties

Formula
C9H9NS
Formula Weight
163.24
Boiling Point
247°
Flash Point
>110°(230°F)
Density
1.085
Refractive Index
1.6250
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Hydrolyzes in water.

Applications

2,6-Dimethylphenyl isocyanate has been used in the preparation of derivatized β-cyclodextrins, used as chiral stationary phase in normal-phase liquid chromatography, tris( 2,6-dimethylphenylimido)methylrhenium (VII), 1-(2-isopropylphenyl)-3-(2,6-dimethylphenyl)urea.

Notes

Moisture Sensitive. Keep container tightly closed. Store away from oxidizing agents.

Literature References

Xuechun Zhang.; Young K. Lee.; James A. Kelley.; Terrence R. Burke. Preparation of Aryl Isothiocyanates via Protected Phenylthiocarbamates and Application to the Synthesis of Caffeic Acid (4-Isothiocyanato)phenyl Ester. J. Org. Chem. 2000, 65, (9), 6237-6240.

Jian Liu.; Raymond J. Patch.; Carsten Schubert.; Mark R. Player. Single-Step Syntheses of 2-Amino-7-chlorothiazolo[5,4-d]pyrimidines:? Intermediates for Bivalent Thiazolopyrimidines. J. Org. Chem. 2005, 70, (24), 10194-10197.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
637195
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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