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19241-16-8 - 2,6-Dimethylphenyl isothiocyanate, 98% - A19480 - Alfa Aesar

A19480 2,6-Dimethylphenyl isothiocyanate, 98%

CAS Number
19241-16-8
Synonyms

Size Price ($) Quantity Availability
5g 55.62
25g 138.40
100g 539.00
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2,6-Dimethylphenyl isothiocyanate, 98%

MDL
MFCD00038715
EINECS
242-906-0

Chemical Properties

Formula
C9H9NS
Formula Weight
163.24
Boiling Point
247°
Flash Point
>110°(230°F)
Density
1.085
Refractive Index
1.6250
Sensitivity
Moisture Sensitive
Solubility
Hydrolyzes in water.

Applications

2,6-Dimethylphenyl isocyanate has been used in the preparation of derivatized β-cyclodextrins, used as chiral stationary phase in normal-phase liquid chromatography, tris( 2,6-dimethylphenylimido)methylrhenium (VII), 1-(2-isopropylphenyl)-3-(2,6-dimethylphenyl)urea.

Notes

Moisture Sensitive. Keep container tightly closed. Store away from oxidizing agents.

Literature References

Xuechun Zhang.; Young K. Lee.; James A. Kelley.; Terrence R. Burke. Preparation of Aryl Isothiocyanates via Protected Phenylthiocarbamates and Application to the Synthesis of Caffeic Acid (4-Isothiocyanato)phenyl Ester. J. Org. Chem. 2000, 65, (9), 6237-6240.

Jian Liu.; Raymond J. Patch.; Carsten Schubert.; Mark R. Player. Single-Step Syntheses of 2-Amino-7-chlorothiazolo[5,4-d]pyrimidines:? Intermediates for Bivalent Thiazolopyrimidines. J. Org. Chem. 2005, 70, (24), 10194-10197.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H314-H318

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
637195
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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