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32247-96-4 - 3,5-Bis(trifluoromethyl)benzyl bromide, 98% - A19590 - Alfa Aesar

A19590 3,5-Bis(trifluoromethyl)benzyl bromide, 98%

CAS Number
32247-96-4
Synonyms

Size Price ($) Quantity Availability
1g 38.20
5g 121.00
25g 395.00
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3,5-Bis(trifluoromethyl)benzyl bromide, 98%

MDL
MFCD00009905
EINECS
250-971-1

Chemical Properties

Formula
C9H5BrF6
Formula Weight
307.04
Boiling Point
136-140°/14mm
Flash Point
>100°(212°F)
Density
1.675
Refractive Index
1.4450
Solubility
Difficult to mix.

Applications

3,5-Bis(trifluoromethyl)benzyl bromide is used as derivatization reagent in detection of uracil in DNA by GC and negative chemical ionization mass spectrometry in enantioselective synthesis of non-peptidic neurokinin NK1 receptor antagonist.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

G Bhaskar.; B Venkateswara Rao. Stereoselective synthesis of L-733,060. Tetrahedron Letters. 2003, 44, (5), 915-917

 

B.C. Blount.; B.N. Ames. Analysis of Uracil in DNA by Gas Chromatography-Mass Spectrometry. Analytical Biochemistry. 1994, 219, (2), 195-200

 

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
656506
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
No

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