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1-Bromo-3-iodobenzene is used in the preparation of 3'-bromo-2,3,4,5,6-pentaethyl-biphenyl by reacting with hex-3-yne. It is also used to prepare 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene. Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.
Kanazawa, Y.; Yokota, T.; Ogasa, H.; Watanabe, H.; Hanakawa, T.; Soga, S.; Kawatsura, M. Chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or ligand-free copper catalysts. Tetrahedron 2015, 71 (9), 1395-1402.
Sharma, R.; Thakur, K.; Kumar, R.; Kumar, I.; Sharma, U. Distant C-H Activation/Functionalization: A New Horizon of Selectivity Beyond Proximity. Catal. Rev. Sci. Eng. 2015, 57 (3), 345-405.
Hazard Statements: H315-H319
Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P280g-P305+P351+P338
Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.