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591-18-4 - 1-Bromo-3-iodobenzene, 98% - 3-Bromoiodobenzene - A19596 - Alfa Aesar

A19596 1-Bromo-3-iodobenzene, 98%

CAS Number
591-18-4
Synonyms
3-Bromoiodobenzene

Size Price ($) Quantity Availability
25g 79.60
100g 274.00
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1-Bromo-3-iodobenzene, 98%

MDL
MFCD00001043
EINECS
209-703-9

Chemical Properties

Formula
C6H4BrI
Formula Weight
282.91
Melting point
-9°
Boiling Point
252°
Flash Point
>110°(230°F)
Density
2.219
Refractive Index
1.6620
Sensitivity
Light Sensitive
Solubility
Immiscible with water.

Applications

1-Bromo-3-iodobenzene is used in the preparation of 3'-bromo-2,3,4,5,6-pentaethyl-biphenyl by reacting with hex-3-yne. It is also used to prepare 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene. Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Notes

Light sensitive. Incompatible with strong oxidizing agents, strong bases and strong acids. Store in a cool place.

Literature References

Kanazawa, Y.; Yokota, T.; Ogasa, H.; Watanabe, H.; Hanakawa, T.; Soga, S.; Kawatsura, M. Chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or ligand-free copper catalysts. Tetrahedron 2015, 71 (9), 1395-1402.

Sharma, R.; Thakur, K.; Kumar, R.; Kumar, I.; Sharma, U. Distant C-H Activation/Functionalization: A New Horizon of Selectivity Beyond Proximity. Catal. Rev. Sci. Eng. 2015, 57 (3), 345-405.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1854384
Harmonized Tariff Code
2903.99
TSCA
Yes

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