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41459-42-1 - 3-Bromo-2-(bromomethyl)propionic acid, 98% - Bis(bromomethyl)acetic acid - A19630 - Alfa Aesar

A19630 3-Bromo-2-(bromomethyl)propionic acid, 98%

CAS Number
41459-42-1
Synonyms
Bis(bromomethyl)acetic acid

Size Price ($) Quantity Availability
5g 60.70
25g 212.00
100g 632.00
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3-Bromo-2-(bromomethyl)propionic acid, 98%

MDL
MFCD00010643

Chemical Properties

Formula
(BrCH2)2CHCO2H
Formula Weight
245.91
Melting point
98-101°
Solubility
Soluble in acetic acid.

Applications

3-Bromo-2-(bromomethyl)propionic acid acts as an organic building block for the preparation of beta-substituted acrylates. It is used in the preparation of t-butyl 2-(phenylthiomethyl) propenoate, t-butyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl-sulfinylmethyl)propenoate. Further, it plays an important role in the synthesis of beta-lactams by cyclization of the corresponding amide.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Zhang, X.; Teixeira, V.; Porcal, W.; Cabral, P.; Gambini, J. P.; Fernandez, M.; Gallazzi, F.; Quinn, T. P. [99mTc(CO)3]+ and [99mTcO2]+ Radiolabeled Cyclic Melanotropin Peptides for Melanoma SPECT Imaging. Curr. Radiopharm. 2014, 7 (1), 63-74.

Hicks, M. R.; Rullay, A. K.; Pedrido, R.; Crout, D. H.; Pinheiro, T. J. T. Efficient Synthesis of Methanesulphonate-Derived Lipid Chains for Attachment of Proteins to Lipid Membranes. Synth. Commun. 2008, 38 (21), 3726-3750.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
No

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