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700-16-3 - Pentafluoropyridine, 99% - A19656 - Alfa Aesar

A19656 Pentafluoropyridine, 99%

CAS Number
700-16-3
Synonyms

Size Price ($) Quantity Availability
5g 39.80
25g 130.00
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Pentafluoropyridine, 99%

MDL
MFCD00006225
EINECS
211-839-9

Chemical Properties

Formula
C5F5N
Formula Weight
169.05
Boiling Point
83-85°
Flash Point
23°(73°F)
Density
1.618
Refractive Index
1.3870
Solubility
Not miscible or difficult to mix in water.

Applications

Pentafluoropyridine was used in the preparation of η2-C,C coordinated pentafluoropyridine complex. It was also used in the preparation of polyfluorinated coupling products via Pd(0)-catalyzed cross-coupling reaction with diarylzinc compounds. It was also used as derivatizing reagent in the sensitive GC-MS method for determination of the four endocrine disrupting chemicals.

Notes

Store away from oxidizing agents, alkali metals and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Procacci B.; Blagg RJ.; Perutz RN, et al. Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction.Organometallics.2014,33(1), 45-52.

Masato Ohashi, et al. Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds.Chemistry.2014,20(7), 2040-2048.

Protection of alcohols has been effected under phase-transfer conditions to give preferentially the 4-alkoxy-derivatives which can be cleaved with sodium methoxide in DMF: J. Chem. Soc., Chem. Commun., 125 (1984).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H226-H302-H312-H332

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1427064
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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