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A19656 Pentafluoropyridine, 99%

CAS Number
700-16-3
Synonyms

Stock No. Size Price ($) Quantity Availability
A19656-06 5g 40.30
A19656-14 25g 133.00
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Pentafluoropyridine, 99%

MDL
MFCD00006225
EINECS
211-839-9

Chemical Properties

Formula
C5F5N
Formula Weight
169.05
Boiling Point
83-85°
Flash Point
23°(73°F)
Density
1.618
Refractive Index
1.3865
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

Pentafluoropyridine was used in the preparation of η2-C,C coordinated pentafluoropyridine complex. It was also used in the preparation of polyfluorinated coupling products via Pd(0)-catalyzed cross-coupling reaction with diarylzinc compounds. It was also used as derivatizing reagent in the sensitive GC-MS method for determination of the four endocrine disrupting chemicals.

Notes

Store away from oxidizing agents, alkali metals and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Procacci B.; Blagg RJ.; Perutz RN, et al. Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction.Organometallics.2014,33(1), 45-52.

Masato Ohashi, et al. Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds.Chemistry.2014,20(7), 2040-2048.

Protection of alcohols has been effected under phase-transfer conditions to give preferentially the 4-alkoxy-derivatives which can be cleaved with sodium methoxide in DMF: J. Chem. Soc., Chem. Commun., 125 (1984).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H312-H314-H332-H335

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1427064
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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