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95201-93-7 - Methyl 4-bromo-3-hydroxythiophene-2-carboxylate, 97% - 4-Bromo-3-hydroxythiophene-2-carboxylic acid methyl ester - B20249 - Alfa Aesar

B20249 Methyl 4-bromo-3-hydroxythiophene-2-carboxylate, 97%

CAS Number
95201-93-7
Synonyms
4-Bromo-3-hydroxythiophene-2-carboxylic acid methyl ester

Size Price ($) Quantity Availability
2.5g 67.36
10g 212.18
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Methyl 4-bromo-3-hydroxythiophene-2-carboxylate, 97%

MDL
MFCD00052081

Chemical Properties

Formula
C6H5BrO3S
Formula Weight
237.08
Melting point
79-80°
Solubility
Sparingly Soluble in water 0.95 g/L @ 25°C.

Applications

The synthesis of the thienopyranone scaffold began with the alkylation of methyl 4-bromo-3-hydroxythiophene-2-carboxylate with N-acetylmorpholine.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents, bases, reducing agents.

Literature References

Guillermo A. Morales; Joseph R. Garlich; Jingdong Su; Xiaodong Peng; Jessica Newblom; Kevin Weber and Donald L. Durden. Synthesis and Cancer Stem Cell-Based Activity of Substituted 5-Morpholino-7H-thieno[3,2-b]pyran-7-ones Designed as Next Generation PI3K Inhibitors. J. Med. Chem. 2013, 56 (5), 1922-1939.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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