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B20272 2',4'-Dihydroxy-3'-methylacetophenone, 98%

CAS Number
10139-84-1
Synonyms

Stock No. Size Price ($) Quantity Availability
B20272-06 5g 51.40
B20272-14 25g 187.00
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2',4'-Dihydroxy-3'-methylacetophenone, 98%

MDL
MFCD00010817

Chemical Properties

Formula
C9H10O3
Formula Weight
166.18
Melting point
152-156°
Storage & Sensitivity
Ambient temperatures.

Applications

chemo selective benzylation of 2,4-dihydroxy-3-methylacetophenone gave the 4-benzyloxy derivative. 4- Ethyl-6 methyl resorcinol was prepared by Clemmensen reduction of 4-dihydroxy-3- methylacetophenone.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

David W. Gammon; Roger Hunter; Seanette A. Wilson. An efficient synthesis of 7-hydroxy-2,6-dimethylchromeno[3,4-d]oxazol-4-one—a protected fragment of novenamine. Tetrahedron. 2005, 61 (45), 10683-10688.

J. P. Brown; D. H. Johnson; Alexander Robertson and W. B. Whalley. 448. Some alkylresorcinols. J. Chem. Soc. 1951, 2019-2020.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2914.50
TSCA
No

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