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chemo selective benzylation of 2,4-dihydroxy-3-methylacetophenone gave the 4-benzyloxy derivative. 4- Ethyl-6 methyl resorcinol was prepared by Clemmensen reduction of 4-dihydroxy-3- methylacetophenone.
David W. Gammon; Roger Hunter; Seanette A. Wilson. An efficient synthesis of 7-hydroxy-2,6-dimethylchromeno[3,4-d]oxazol-4-onea protected fragment of novenamine. Tetrahedron. 2005, 61 (45), 10683-10688.
J. P. Brown; D. H. Johnson; Alexander Robertson and W. B. Whalley. 448. Some alkylresorcinols. J. Chem. Soc. 1951, 2019-2020.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.