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4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
Dhakshinamoorthy, A.; Latorre-Sanchez, M.; Asiri, A. M.; Primo, A.; Garcia, H. Sulphur-doped graphene as metal-free carbocatalysts for the solventless aerobic oxidation of styrenes. Catal. Commun. 2015, 65, 10-13.
Wang, B.; Lee, Y. M.; Seo, M. S.; Nam, W. Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions. Angew. Chem. Int. Ed. 2015, 54 (40), 11740-11744.
Hazard Statements: H227-H302-H315-H319
Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P210-P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant