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3-Ethoxysalicylaldehyde is employed in the preparation of Schiff base ligand through condensation with trans-1,2-diaminocyclohexane. It is also useful for the preparation of substituted salen-type Schiff base ligands. Further, it is used to prepare 2-ethoxy-6-[(3-methylaminopropylimino)methyl]phenol by reaction with N-methylpropane-1,3-diamine.
Tigineh, G. T.; Wen, Y. S.; Liu, L. K. Solvent-free mechanochemical conversion of 3-ethoxysalicylaldehyde and primary aromatic amines to corresponding Schiff-bases. Tetrahedron 2015, 71 (1), 170-175.
Chakraborty, P.; Mohanta, S. Syntheses, structures and catecholase activity of two cobalt(III) complexes derived from N,N'-ethylenebis(3-ethoxysalicylaldiimine): A special host-guest system from a special ligand. Inorg. Chim. Acta 2015, 435, 38-45.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant