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B20703 4-Allyl-1,6-heptadien-4-ol, 99%

CAS Number
10202-75-2
Synonyms
Triallyl carbinol

Stock No. Size Price ($) Quantity Availability
B20703-88 2.5g 28.80
B20703-09 10g 80.10
B20703-18 50g 307.00
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4-Allyl-1,6-heptadien-4-ol, 99%

MDL
MFCD00039829

Chemical Properties

Formula
(CH2=CHCH2)3COH
Formula Weight
152.24
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.

Notes

Store at room temperature. Incompatible with strong oxidizing agents.

Literature References

Hongjun Ren.; Guillaume Dunet.; Peter Mayer.; Paul Knochel. Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents.J. Am. Chem. Soc. 2007, 129 (17),5376-5377 .

Robert J. Hinkle.; Alessandra C. Leri.; Geoffrey A. David. ;Whitney M. Erwin. Addition of Benzylzinc Halides to Alkenyl(phenyl)iodonium Triflates:? Stereoselective Synthesis of Trisubstituted Alkenes.Org. Lett.. 2000, 2 (11),1521-1523 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2905.29
TSCA
No

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