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10202-75-2 - 4-Allyl-1,6-heptadien-4-ol, 99% - Triallyl carbinol - B20703 - Alfa Aesar

B20703 4-Allyl-1,6-heptadien-4-ol, 99%

CAS Number
10202-75-2
Synonyms
Triallyl carbinol

Size Price ($) Quantity Availability
2.5g 31.93
10g 69.76
50g 269.60
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4-Allyl-1,6-heptadien-4-ol, 99%

MDL
MFCD00039829

Chemical Properties

Formula
(CH2=CHCH2)3COH
Formula Weight
152.24
Solubility
Soluble in water.

Applications

A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.

Notes

Store at room temperature. Incompatible with strong oxidizing agents.

Literature References

Hongjun Ren.; Guillaume Dunet.; Peter Mayer.; Paul Knochel. Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents.J. Am. Chem. Soc. 2007, 129 (17),5376-5377 .

Robert J. Hinkle.; Alessandra C. Leri.; Geoffrey A. David. ;Whitney M. Erwin. Addition of Benzylzinc Halides to Alkenyl(phenyl)iodonium Triflates:? Stereoselective Synthesis of Trisubstituted Alkenes.Org. Lett.. 2000, 2 (11),1521-1523 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2905.29
TSCA
No

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