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B20788 Ethyl 5-bromonicotinate, 98%

CAS Number
20986-40-7
Synonyms
5-Bromonicotinic acid ethyl ester
Ethyl 5-bromopyridine-3-carboxylate

Stock No. Size Price ($) Quantity Availability
B20788-03 1g 47.10
B20788-06 5g 180.00
B20788-14 25g 702.00
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Ethyl 5-bromonicotinate, 98%

MDL
MFCD00040366

Chemical Properties

Formula
C8H8BrNO2
Formula Weight
230.07
Melting point
39-42°
Boiling Point
86-92°/0.5mm
Storage & Sensitivity
Ambient temperatures.

Applications

Ethyl 5-bromonicotinate is used as a key starting material for the preparation of 5-bromonicotinic acid hydrazide via reaction with a hydrazine hydrate.

Notes

Incompatible with oxidizing agents.

Literature References

Houllier, N.; Lasne, M. C.; Bureau, R.; Lestage, P.; Rouden, J. Synthesis of a cytisine/epibatidine hybrid: a radical approach. Tetrahedron 2010, 66 (47), 9231-9241.

Melzig, L.; Dennenwaldt, T.; Gavryushin, A.; Knochel, P. Direct aminoalkylation of arenes, heteroarenes, and alkenes via Ni-catalyzed Negishi cross-coupling reactions. J. Org. Chem 2011, 76 (21), 8891-8906.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
131473
Harmonized Tariff Code
2933.39
TSCA
No

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