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20986-40-7 - Ethyl 5-bromonicotinate, 98% - 5-Bromonicotinic acid ethyl ester - Ethyl 5-bromopyridine-3-carboxylate - B20788 - Alfa Aesar

B20788 Ethyl 5-bromonicotinate, 98%

CAS Number
20986-40-7
Synonyms
5-Bromonicotinic acid ethyl ester
Ethyl 5-bromopyridine-3-carboxylate

Size Price ($) Quantity Availability
1g 45.70
5g 176.00
25g 688.00
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Ethyl 5-bromonicotinate, 98%

MDL
MFCD00040366

Chemical Properties

Formula
C8H8BrNO2
Formula Weight
230.07
Melting point
39-42°
Boiling Point
86-92°/0.5mm

Applications

Ethyl 5-bromonicotinate is used as a key starting material for the preparation of 5-bromonicotinic acid hydrazide via reaction with a hydrazine hydrate.

Notes

Incompatible with oxidizing agents.

Literature References

Houllier, N.; Lasne, M. C.; Bureau, R.; Lestage, P.; Rouden, J. Synthesis of a cytisine/epibatidine hybrid: a radical approach. Tetrahedron 2010, 66 (47), 9231-9241.

Melzig, L.; Dennenwaldt, T.; Gavryushin, A.; Knochel, P. Direct aminoalkylation of arenes, heteroarenes, and alkenes via Ni-catalyzed Negishi cross-coupling reactions. J. Org. Chem 2011, 76 (21), 8891-8906.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
131473
Harmonized Tariff Code
2933.39
TSCA
No

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