Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

29681-44-5 - Methyl 5-bromonicotinate, 97% - 5-Bromopyridine-3-carboxylic acid methyl ester - Methyl 5-bromopyridine-3-carboxylate - B20908 - Alfa Aesar

B20908 Methyl 5-bromonicotinate, 97%

CAS Number
29681-44-5
Synonyms
5-Bromopyridine-3-carboxylic acid methyl ester
Methyl 5-bromopyridine-3-carboxylate

Size Price ($) Quantity Availability
1g 26.47
5g 106.09
Add to Cart Add to Quote Request View Item

Methyl 5-bromonicotinate, 97%

MDL
MFCD00173668

Chemical Properties

Formula
C7H6BrNO2
Formula Weight
216.04
Melting point
96-98°
Solubility
Slightly soluble in water.

Applications

A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Wayne J. Thompson, et al. A general synthesis of 5-arylnicotinates.J. Org. Chem.,1984,49(26), 5237-5243.

Masahiko Iyoda, et al. Homocoupling of Aryl Halides Using Nickel(II) Complex and Zinc in the Presence of Et4NI. An Efficient Method for the Synthesis of Biaryls and Bipyridines.Bull. Chem. Soc. Jpn.,1990,63(1), 80-87.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2933.39
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware