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B20931 2-(Difluoromethoxy)benzyl bromide, 97%

CAS Number
85684-64-6
Synonyms
alpha-Bromo-2-difluoromethoxytoluene

Stock No. Size Price ($) Quantity Availability
B20931-09 10g 271.00
B20931-18 50g 1144.00
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2-(Difluoromethoxy)benzyl bromide, 97%

MDL
MFCD00190103

Chemical Properties

Formula
C8H7BrF2O
Formula Weight
237.04
Boiling Point
222°
Flash Point
108°(228°F)
Density
1.555
Refractive Index
1.5180
Storage & Sensitivity
Ambient temperatures.
Solubility
Immiscible with water.

Applications

2-(Difluoromethoxy)benzyl bromide is used as a building block in organic synthesis. It also serves as a coupling reagent and N-protecting reagent. Further, it is used as a gas chromatography derivatizing agent.

Notes

Incompatible with oxidizing agents, strong bases, alcohols and ammonia.

Literature References

Madaiah, M.; Prashanth, M. K.; Revanasiddappa, H. D.; Veeresh, B. Synthesis and Pharmacological Evaluation of Novel 1'-[2-(Difluoromethoxy)benzyl]-2'H,5'H-spiro[8-azabicyclo[3.2.1]octane-3,4'-imidazolidine]-2',5'-diones and Their Derivatives. Arch. Pharm. 2014, 347 (5), 370-380.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2909.30
TSCA
No

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