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It is employed in the replacement of nuclear alkoxyl groups to yield dimethoxy ketones by the action of methyl and phenyl Grignard reagents on 2,3-dimethoxybenzonitrile.
A. I. Meyers, et al. Oxazolines. XXII. Nucleophilic aromatic substitution on aryl oxazolines. Efficient approach to unsymmetrically substituted biphenyls and o-alkyl benzoic acids.J. Am. Chem. Soc.,1975,97(25), 7383-7385.
Stefan Rudolf Kaschabek and Walter Reineke. Synthesis of Bacterial Metabolites from Haloaromatic Degradation. 1. Fe(III)-Catalyzed Peracetic Acid Oxidation of Halocatechols, a Facile Entry to cis,cis-2-Halo-2,4-hexadienedioic Acids and 3-Halo-5-oxo-2(5H)-furanylideneacetic Acids.J. Org. Chem.,1994,59(14), 4001-4003.
Hazard Statements: H302-H312-H331-H315-H319-H335
Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.