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B20958 Perfluoro-1-iodohexane, 98+%, stab. with copper

CAS Number
355-43-1
Synonyms
1-Iodoperfluorohexane
Perfluoro-n-hexyl iodide

Stock No. Size Price ($) Quantity Availability
B20958-09 10g 34.60
B20958-18 50g 129.00
B20958-30 250g 519.00
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Perfluoro-1-iodohexane, 98+%, stab. with copper

MDL
MFCD00001063
EINECS
206-586-6

Chemical Properties

Formula
CF3(CF2)5I
Formula Weight
445.95
Melting point
-45°
Boiling Point
117°
Density
2.063
Refractive Index
1.3290
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.

Notes

Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Qian Liu, et al. Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalyst fac-[Ir(ppy)]3.J. Polym. Sci.,2014,52(22), 3283-3291.

Emily R. Berkeley,et al. Syntheses, Structural Characterizations, and Reactivity Studies of Half-Sandwich Cobalt, Rhodium, and Iridium Metallatricarbadecaboranyl Complexes.Organometallics.,2015,34(7), 1396-1407.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1802118
Harmonized Tariff Code
2903.78
TSCA
Yes

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