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355-43-1 - Perfluoro-1-iodohexane, 98+%, stab. with copper - 1-Iodoperfluorohexane - Perfluoro-n-hexyl iodide - B20958 - Alfa Aesar

B20958 Perfluoro-1-iodohexane, 98+%, stab. with copper

CAS Number
355-43-1
Synonyms
1-Iodoperfluorohexane
Perfluoro-n-hexyl iodide

Size Price ($) Quantity Availability
10g 35.90
50g 138.00
250g 546.00
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Perfluoro-1-iodohexane, 98+%, stab. with copper

MDL
MFCD00001063
EINECS
206-586-6

Chemical Properties

Formula
CF3(CF2)5I
Formula Weight
445.95
Melting point
-45°
Boiling Point
117°
Density
2.063
Refractive Index
1.3290
Sensitivity
Light Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.

Notes

Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Qian Liu, et al. Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalyst fac-[Ir(ppy)]3.J. Polym. Sci.,2014,52(22), 3283-3291.

Emily R. Berkeley,et al. Syntheses, Structural Characterizations, and Reactivity Studies of Half-Sandwich Cobalt, Rhodium, and Iridium Metallatricarbadecaboranyl Complexes.Organometallics.,2015,34(7), 1396-1407.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1802118
Harmonized Tariff Code
2903.78
TSCA
Yes

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