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823-76-7 - Cyclohexyl methyl ketone, 95% - Acetylcyclohexane - Hexahydroacetophenone - B21000 - Alfa Aesar

B21000 Cyclohexyl methyl ketone, 95%

CAS Number
823-76-7
Synonyms
Acetylcyclohexane
Hexahydroacetophenone

Size Price ($) Quantity Availability
5g 33.00
25g 101.00
100g 335.00
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Cyclohexyl methyl ketone, 95%

MDL
MFCD00040418
EINECS
212-517-0

Chemical Properties

Formula
C8H14O
Formula Weight
126.20
Melting point
-34°
Boiling Point
181-183°
Flash Point
66°(151°F)
Density
0.917
Refractive Index
1.4520
Solubility
Not miscible or difficult to mix in water.

Applications

It can be used to produce acetoxycyclohexane. It is also used as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Bach RD. The role of acid catalysis in the Baeyer-Villiger reaction. A theoretical study.J Org Chem.201277(16), 6801-15.

Thomas M. Bare and Herbert O. House. Methyl Ketones from Carboxylic Acids: Cyclohexyl Methyl Ketone.Org. Synth.

Monobromination of unsymmetrical ketones at the less-substituted carbon atom in methanol gives results which parallel the bromination of the corresponding acetal, and in this case results in exclusive reaction at the methyl group: Org. Synth. Coll., 6, 193 (1988).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210u-P261-P280a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
507229
Harmonized Tariff Code
2914.29
TSCA
No
RTECS
KM5638850

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