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1623-93-4 - Biphenyl-4-sulfonyl chloride, 97% - 4-Phenylbenzenesulfonyl chloride - B21031 - Alfa Aesar

B21031 Biphenyl-4-sulfonyl chloride, 97%

CAS Number
1623-93-4
Synonyms
4-Phenylbenzenesulfonyl chloride

Size Price ($) Quantity Availability
5g 46.17
25g 150.40
100g 492.80
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Biphenyl-4-sulfonyl chloride, 97%

MDL
MFCD00078658
EINECS
216-609-1

Chemical Properties

Formula
C12H9ClO2S
Formula Weight
252.72
Melting point
112-117°
Boiling Point
200-205°/6mm
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

It is a reactant for preparation of anilinopyrimidinesulfonamides as potential anticancer agents, synthesis of inhibitors of the hypoxia inducible factor pathway. It participates in the preparation of hydroxy-sulfonyl-piperidinyl butyramides as HDAC inhibitors and potential antitumors and is also involved in palladium-catalyzed desulfitative C-arylation.

Notes

Store at room temperature. Keep away from moisture, bases and oxidizing agents.

Literature References

Srinivas Reddy Dubbaka.;Pierre Vogel. Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Sulfonyl Chlorides and Boronic Acids. Org. Lett. 2004, 6 (1),95-98 .

Srinivas Reddy Dubbaka.; Pierre Vogel. Palladium-Catalyzed Stille Cross-Couplings of Sulfonyl Chlorides and Organostannanes.J. Am. Chem. Soc. 2003, 125 (50),15292-15293 .

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2694373
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.90
TSCA
No

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