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B21054 1,5-Bis(diphenylphosphino)pentane, 97%

CAS Number
27721-02-4
Synonyms

Stock No. Size Price ($) Quantity Availability
B21054-03 1g 33.20
B21054-06 5g 119.00
B21054-14 25g 537.00
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1,5-Bis(diphenylphosphino)pentane, 97%

MDL
MFCD00003052

Chemical Properties

Formula
(C6H5)2P(CH2)5P(C6H5)2
Formula Weight
440.50
Melting point
46-48°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in N,N-dimethyl formamide.

Applications

1,5-Bis(diphenylphosphino)pentane is used as a ligand for the cross coupling reactions. It is used in the manufacturing of glass bottle PTFE bottle, aluminum foil bag and in cardboard drum. combination of a 1,5-bis(diphenylphosphino)pentane ligand and the addition of N,N,N?,N?-tetramethylethylenediamine (TMEDA) as a co-catalyst are the key factors in obtaining the corresponding aryl nitriles with improved catalyst productivities and selectivities.

Notes

Store at room temperature. Keep away from oxidizing agents.

Literature References

Edit Farkas.; László Kollár.; Massimo Moret.; Angelo Sironi. Halogen Exchange in Platinum-Phosphine-Tin(II) Halide Systems. Characterization of the Novel PtI(SnCl3)[(2S,4S)-2,4-bis(diphenylphosphino)pentane] Complex. Organometallics. 1996, 15 (5),1345-1350 .

Thomas Schareina.;Alexander Zapfa.; Matthias Beller. Potassium hexacyanoferrate(II)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides. Chem. Commun. 2004, < (12),1388-1389 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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