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13991-08-7 - 1,2-Bis(diphenylphosphino)benzene, 98% - B21106 - Alfa Aesar

B21106 1,2-Bis(diphenylphosphino)benzene, 98%

CAS Number
13991-08-7
Synonyms

Size Price ($) Quantity Availability
0.25g 35.70
1g 94.50
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1,2-Bis(diphenylphosphino)benzene, 98%

MDL
MFCD00014081

Chemical Properties

Formula
C26H22P2
Formula Weight
446.47
Melting point
185-189°
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

It acts as a ligand for Baeyer-Villiger Oxidation, cycloadditions and reductions.

Notes

Air sensitive. Store away from air and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

Akira Tsuboyama, et al. Photophysical Properties of Highly Luminescent Copper(I) Halide Complexes Chelated with 1,2-Bis(diphenylphosphino)benzene.Inorg. Chem.,200746(6), 1992-2001.

Takuji Hatakeyama, et al. Iron-catalyzed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene.Chem. Commun.,2009,(10), 1216-1218.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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