Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97%

CAS Number
12150-46-8
Synonyms
Dppf
1,1'-Ferrocenebis(diphenylphosphine)

Stock No. Size Price ($) Quantity Availability
B21166-03 1g 35.10
B21166-06 5g 101.00
B21166-14 25g 446.00
Add to Cart Bulk/Specialty Print Quote View Item

1,1'-Bis(diphenylphosphino)ferrocene, 97%

MDL
MFCD00001422

Chemical Properties

Formula
C34H28FeP2
Formula Weight
554.40
Melting point
ca 182° dec.
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Applications

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Notes

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).

Li, C. G.; Xue, F.; Cui, M. J.; Shang, J. Y.; Lou, T. J. 1,1'-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons. Transition Met. Chem. 2015, 40 (1), 47-52.

Kaur-Ghumaan, S.; Sreenithya, A.; Sunoj, R. B. Synthesis, characterization and DFT studies of 1, 1'-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes. J. Chem. Sci. 2015, 127 (3), 557-563.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H332

Toxic if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

  • A10807

    1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride, 98+%
  • A11767

    Trifluoromethanesulfonic anhydride, 98%
  • A12931

    1,3-Bis(diphenylphosphino)propane, 97%
  • A17847

    L-Isoleucine methyl ester hydrochloride, 98+%
  • 12760

    Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware