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B21272 2-Bromo-4,6-dimethylaniline, 98%

CAS Number
41825-73-4
Synonyms

Stock No. Size Price ($) Quantity Availability
B21272-09 10g 44.50
B21272-14 25g 84.50
B21272-18 50g 148.00
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2-Bromo-4,6-dimethylaniline, 98%

MDL
MFCD00047826
EINECS
246-337-9

Chemical Properties

Formula
C8H10BrN
Formula Weight
200.08
Melting point
42-46°
Boiling Point
75-79°/5mm
Flash Point
>110°(230°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

2-Bromo-4,6-dimethylaniline can react with 3-chloro-3-methyl-but-1-yne to produce 2-bromo-N-(1',1'-dimethylprop-2'-ynyl)-4,6-dimethylaniline. This reaction will need reagent Et3N, catalyst CuCl, and the menstruum dioxane.

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

Rattan K. Gujadhur.; Craig G. Bates.; D. Venkataraman. Formation of Aryl-Nitrogen, Aryl-Oxygen, and Aryl-Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts. Org. Lett. 2001, 3, (26), 4315-4317.

Fuk Yee Kwong.; Artis Klapars.; Stephen L. Buchwald. Copper-Catalyzed Coupling of Alkylamines and Aryl Iodides:? An Efficient System Even in an Air Atmospheres. Org. Lett. 2002, 4, (4), 581-584.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H373

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P314-P330-P332+P313-P337+P313-P362-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3046484
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.42
TSCA
No

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