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718-64-9 - 1,1,1,3,3,3-Hexafluoro-2-phenyl-2-propanol, 98+% - alpha,alpha-Bis(trifluoromethyl)benzyl alcohol - Hexafluorocumyl alcohol - B21366 - Alfa Aesar

B21366 1,1,1,3,3,3-Hexafluoro-2-phenyl-2-propanol, 98+%

CAS Number
718-64-9
Synonyms
alpha,alpha-Bis(trifluoromethyl)benzyl alcohol
Hexafluorocumyl alcohol

Size Price ($) Quantity Availability
1g 13.84
5g 49.50
25g 160.20
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1,1,1,3,3,3-Hexafluoro-2-phenyl-2-propanol, 98+%

MDL
MFCD00040983
EINECS
211-943-4

Chemical Properties

Formula
C9H6F6O
Formula Weight
244.14
Boiling Point
159-160°
Flash Point
60°(140°F)
Density
1.450
Refractive Index
1.4150

Literature References

Protection of primary and secondary alcohols as hexafluorophenylisopropyl (HIP) ethers can be effected under Mitsunobu conditions. The HIP group shows outstanding chemical resistance under a wide pH range and also in the presence of nucleophiles, organometallic reagents, oxidants, reducing agents and Lewis acids. Selective deprotection with Li naphthalenide is effective, even at -78o: J. Am. Chem. Soc., 116, 8354 (1994).

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GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2053547
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2906.29
TSCA
Yes

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