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B21579 Ethyl bromofluoroacetate, 97%

CAS Number
401-55-8
Synonyms
Bromofluoroacetic acid ethyl ester

Stock No. Size Price ($) Quantity Availability
B21579-03 1g 17.20
B21579-06 5g 39.20
B21579-14 25g 140.00
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Ethyl bromofluoroacetate, 97%

MDL
MFCD00042095
EINECS
206-928-4

Chemical Properties

Formula
FBrCHCO2CH2CH3
Formula Weight
184.99
Boiling Point
154°
Flash Point
70°(158°F)
Density
1.540
Refractive Index
1.4255
Storage & Sensitivity
Ambient temperatures.
Solubility
It is soluble in water.

Applications

Ethyl bromofluoroacetate is used as an intermediate useful in the synthesis of polyfluoroalkyl-substituted fluoro enol ethers and N-protected α-fluoroglycines.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literature References

R Ocampo.; WR Dolbier.; KA Abboud. Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of α-fluoro-β-hydroxy acids. J. Org. Chem. 200267 (1), 72-78.

Undergoes Reformatsky reactions with Zn and carbonyl compounds under various conditions. Superior results have been obtained in the presence of a catalytic amount of CeCl3: J. Org. Chem., 67, 72 (2002):

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302+H312+H332-H315-H319-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
No

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