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401-55-8 - Ethyl bromofluoroacetate, 97% - Bromofluoroacetic acid ethyl ester - B21579 - Alfa Aesar

B21579 Ethyl bromofluoroacetate, 97%

CAS Number
401-55-8
Synonyms
Bromofluoroacetic acid ethyl ester

Size Price ($) Quantity Availability
1g 16.10
5g 37.50
25g 138.00
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Ethyl bromofluoroacetate, 97%

MDL
MFCD00042095
EINECS
206-928-4

Chemical Properties

Formula
FBrCHCO2CH2CH3
Formula Weight
184.99
Boiling Point
154°
Flash Point
70°(158°F)
Density
1.540
Refractive Index
1.4255
Solubility
It is soluble in water.

Applications

Ethyl bromofluoroacetate is used as an intermediate useful in the synthesis of polyfluoroalkyl-substituted fluoro enol ethers and N-protected α-fluoroglycines.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literature References

R Ocampo.; WR Dolbier.; KA Abboud. Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of α-fluoro-β-hydroxy acids. J. Org. Chem. 200267 (1), 72-78.

Undergoes Reformatsky reactions with Zn and carbonyl compounds under various conditions. Superior results have been obtained in the presence of a catalytic amount of CeCl3: J. Org. Chem., 67, 72 (2002):

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H301-H311-H331-H315-H318-H335

Combustible liquid. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
No

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