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421-83-0 - Trifluoromethanesulfonyl chloride, 98% - Trifluoromethylsulfonyl chloride - Triflyl chloride - B21774 - Alfa Aesar

B21774 Trifluoromethanesulfonyl chloride, 98%

CAS Number
421-83-0
Synonyms
Trifluoromethylsulfonyl chloride
Triflyl chloride

Size Price ($) Quantity Availability
5g 52.70
25g 176.00
100g 711.00
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Trifluoromethanesulfonyl chloride, 98%

MDL
MFCD00007451
EINECS
207-009-0

Chemical Properties

Formula
CF3SO2Cl
Formula Weight
168.52
Boiling Point
32°
Density
1.593
Refractive Index
1.3340
Sensitivity
Moisture Sensitive
Solubility
Hydrolyzes with water.

Applications

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

Notes

Moisture sensitive. Store away from water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Nobumasa Kamigata; Takeshi Ohtsuka; Takamasa Fukushima; Masato Yoshida; and Toshio Shimizu. Direct perfluoroalkylation of aromatic and heteroaromatic compounds with perfluoroalkanesulfonyl chlorides catalyzed by a ruthenium(II) phosphine complex.J. Chem. Soc., Perkin Trans. 1.19941339-1346.

Nobumasa Kamigata;Takamasa Fukushima; Yoshie Terakawa; Masato Yoshida; and Hideo Sawada. Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalyzed by a ruthenium(II) complex.J. Chem. Soc., Perkin Trans. 1.1991(3), 627-633.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1812016
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.99
TSCA
No

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