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B21774 Trifluoromethanesulfonyl chloride, 98%

CAS Number
421-83-0
Synonyms
Trifluoromethylsulfonyl chloride
Triflyl chloride

Stock No. Size Price ($) Quantity Availability
B21774-06 5g 54.80
B21774-14 25g 183.00
B21774-22 100g 733.00
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Trifluoromethanesulfonyl chloride, 98%

MDL
MFCD00007451
EINECS
207-009-0

Chemical Properties

Formula
CF3SO2Cl
Formula Weight
168.52
Boiling Point
32°
Density
1.593
Refractive Index
1.3340
Storage & Sensitivity
Keep Cold. Moisture Sensitive.
Solubility
Hydrolyzes with water.

Applications

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

Notes

Moisture sensitive. Store away from water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Nobumasa Kamigata; Takeshi Ohtsuka; Takamasa Fukushima; Masato Yoshida; and Toshio Shimizu. Direct perfluoroalkylation of aromatic and heteroaromatic compounds with perfluoroalkanesulfonyl chlorides catalyzed by a ruthenium(II) phosphine complex.J. Chem. Soc., Perkin Trans. 1.19941339-1346.

Nobumasa Kamigata;Takamasa Fukushima; Yoshie Terakawa; Masato Yoshida; and Hideo Sawada. Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalyzed by a ruthenium(II) complex.J. Chem. Soc., Perkin Trans. 1.1991(3), 627-633.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1812016
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.99
TSCA
No

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