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Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.
Nobumasa Kamigata; Takeshi Ohtsuka; Takamasa Fukushima; Masato Yoshida; and Toshio Shimizu. Direct perfluoroalkylation of aromatic and heteroaromatic compounds with perfluoroalkanesulfonyl chlorides catalyzed by a ruthenium(II) phosphine complex.J. Chem. Soc., Perkin Trans. 1.19941339-1346.
Nobumasa Kamigata;Takamasa Fukushima; Yoshie Terakawa; Masato Yoshida; and Hideo Sawada. Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalyzed by a ruthenium(II) complex.J. Chem. Soc., Perkin Trans. 1.1991(3), 627-633.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.