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B22004 4-(1-Cyclohexen-1-yl)morpholine, 97%

CAS Number
670-80-4
Synonyms
1-(4-Morpholino)cyclohexene
1-(4-Morpholinyl)cyclohexene

Stock No. Size Price ($) Quantity Availability
B22004-14 25g 22.70
B22004-22 100g 75.20
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4-(1-Cyclohexen-1-yl)morpholine, 97%

MDL
MFCD00006163
EINECS
211-579-6

Chemical Properties

Formula
C10H17NO
Formula Weight
167.25
Boiling Point
118-120°/10mm
Flash Point
68°(154°F)
Density
1.020
Refractive Index
1.5146
Storage & Sensitivity
Store under Nitrogen. Keep Cold.

Literature References

Useful synthetic intermediate by reaction at the 2-position with various electrophiles. Reviews: Applications of enamines in organic synthesis: Synthesis, 510 (1970). Synthesis of carbonyl compounds from enamines by alkylation, acylation or addition to Michael acceptors: Synthesis, 517 (1983). Advances in enamine chemistry: Tetrahedron, 38, 1975, 3363 (1982). For an example of C-acylation using an acid chloride in the presence of triethylamine, see: Org. Synth. Coll., 5, 533 (1973).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
118696
Harmonized Tariff Code
2934.99
TSCA
Yes

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