Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

2754-27-0 - Trimethylsilyl acetate, 97% - Acetic acid trimethylsilyl ester - Acetoxytrimethylsilane - B22037 - Alfa Aesar

B22037 Trimethylsilyl acetate, 97%

CAS Number
2754-27-0
Synonyms
Acetic acid trimethylsilyl ester
Acetoxytrimethylsilane

Size Price ($) Quantity Availability
25g 25.30
100g 73.10
Add to Cart Add to Quote Request View Item

Trimethylsilyl acetate, 97%

MDL
MFCD00008695
EINECS
220-404-2

Chemical Properties

Formula
C5H12O2Si
Formula Weight
132.24
Melting point
-32°
Boiling Point
107°
Flash Point
4°(39°F)
Density
0.884
Refractive Index
1.3880
Sensitivity
Moisture Sensitive

Literature References

Lithiation and acylation give the TMS esters of ß-keto acids, which can be converted to the unstable ß-keto acids themselves, or directly to methyl ketones: Synth. Commun., 13, 183 (1983).

/n

Has been used in a 2-carbon homologation sequence for the synthesis of (E)-alkenoic acids via silyl ketene acetals: J. Org. Chem., 63, 8785 (1998):

/n

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1744463
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware