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Triethoxysilane is raw material for synthesis of silane addition agent and silicon oil. It is used as a reducing agent.
Miki Murata; Masanori Ishikura; Masayuki Nagata; Shinji Watanabe; and Yuzuru Masuda. Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane:? Practical Synthetic Route to Aryltriethoxysilanes. Org. Lett. 2002, 4 (11), 1843-1845.
Amy S. Manoso and Philip DeShong. Improved Synthesis of Aryltriethoxysilanes via Palladium(0)-Catalyzed Silylation of Aryl Iodides and Bromides with Triethoxysilane. J. Org. Chem. 2001, 66 (22), 7449-7455.
In the presence of KF or CsF, reduces aldehydes and ketones to alcohols (via the silyl ether): Tetrahedron, 37, 2165 (1981). With CsF, enones can be reduced selectively to allylic alcohols in high yield: Tetrahedron., 39, 999 (1983).
Versatile hydrosilylating agent. For use in combination with Ti(O-i-Pr) 4 in a catalytic system for reduction of esters to alcohols, see: J. Org. Chem ., 57, 3751 (1992). CAUTION! Highly pyrophoric SiH 4 can form in this reaction: J. Org. Chem., 57, 3221 (1993).
The same system effects the otherwise difficult reduction of phosphine oxides to phosphines. The products may be reacted in situ with alkyl halides to give a convenient one-pot conversion of phosphine oxides to phosphonium salts: Tetrahedron Lett., 35, 625 (1994).
Pd(0)-catalyzed silylation of aryl iodides provides a route to aryl triethoxysilanes: J. Org. Chem., 62, 8569 (1997).
Hazard Statements: H226-H302-H315-H318-H330-H335
Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Fatal if inhaled. May cause respiratory irritation.
Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P284-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P314-P330-P332+P313-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant