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B22214 1-Iodooctane, 98+%, stab. with copper

CAS Number
629-27-6
Synonyms
n-Octyl iodide

Stock No. Size Price ($) Quantity Availability
B22214-14 25g 28.30
B22214-22 100g 67.60
B22214-36 500g 258.00
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1-Iodooctane, 98+%, stab. with copper

MDL
MFCD00001105
EINECS
211-084-5

Chemical Properties

Formula
C8H17I
Formula Weight
240.13
Melting point
-46°
Boiling Point
225-226°
Flash Point
95°(203°F)
Density
1.325
Refractive Index
1.4878
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light, bases.

Literature References

Raess PW, et al. J. . Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen. Electroanal. Chem. 2007, 603 (1), 124-34.

Danielle M Goken,; Dennis G Peters,; Jonathan A Karty,; James P Reilly. Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II) during catalytic reduction of 1-iodooctane. Journal of Electroanalytical Chemistry. 2004, 564 123-132.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1697479
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
RG9700100

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