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B22237 Allylchlorodimethylsilane, 95%

CAS Number
4028-23-3
Synonyms
ADMSCl
Allyldimethylchlorosilane

Stock No. Size Price ($) Quantity Availability
B22237-06 5g 59.60
B22237-09 10g 102.00
B22237-14 25g 210.00
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Allylchlorodimethylsilane, 95%

MDL
MFCD00000506
EINECS
223-706-2

Chemical Properties

Formula
C5H11ClSi
Formula Weight
134.68
Boiling Point
110-112°
Flash Point
5°(41°F)
Density
0.896
Refractive Index
1.4290
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in most organic solvents; reacts with alcohols, amines, and water.

Applications

Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1?,4,4?-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.

Notes

Moisture sensitive. Store away from strong oxidizing agents, strong bases, water/ moisture.

Literature References

K. A. Abboud; D. W. Smith Jnr and K. B. Wagener. 3Structure of cyclo-1,1',4,4'-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene. Acta Cryst.. 1993, 53 (49), 1845-1848.

Yoshimoto Abe; Takahiro Gunji. Oligo- and polysiloxanes. Progress in Polymer Science. 2004, 29 (3), 149-182.

Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1737978
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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