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4028-23-3 - Allylchlorodimethylsilane, 95% - ADMSCl - Allyldimethylchlorosilane - B22237 - Alfa Aesar

B22237 Allylchlorodimethylsilane, 95%

CAS Number
4028-23-3
Synonyms
ADMSCl
Allyldimethylchlorosilane

Size Price ($) Quantity Availability
5g 55.70
10g 95.40
25g 201.00
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Allylchlorodimethylsilane, 95%

MDL
MFCD00000506
EINECS
223-706-2

Chemical Properties

Formula
C5H11ClSi
Formula Weight
134.68
Boiling Point
110-112°
Flash Point
5°(41°F)
Density
0.896
Refractive Index
1.4290
Sensitivity
Moisture Sensitive
Solubility
Soluble in most organic solvents; reacts with alcohols, amines, and water.

Applications

Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1?,4,4?-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.

Notes

Moisture sensitive. Store away from strong oxidizing agents, strong bases, water/ moisture.

Literature References

K. A. Abboud; D. W. Smith Jnr and K. B. Wagener. 3Structure of cyclo-1,1',4,4'-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene. Acta Cryst.. 1993, 53 (49), 1845-1848.

Yoshimoto Abe; Takahiro Gunji. Oligo- and polysiloxanes. Progress in Polymer Science. 2004, 29 (3), 149-182.

Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1737978
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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