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B22280 (Phenylthio)acetic acid, 97%

CAS Number
103-04-8
Synonyms
(Phenylmercapto)acetic acid
Thiophenoxyacetic acid

Stock No. Size Price ($) Quantity Availability
B22280-14 25g 47.60
B22280-22 100g 134.00
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(Phenylthio)acetic acid, 97%

MDL
MFCD00004355
EINECS
203-073-9

Chemical Properties

Formula
C6H5SCH2CO2H
Formula Weight
168.22
Melting point
61-66°
Storage & Sensitivity
Ambient temperatures.

Literature References

The dilithio-derivative can be ɑ-monoalkylated in high yield, and the process repeated to give the dialkyl derivative: J. Chem. Soc., Chem. Commun., 714 (1975). Reaction of the dianion with terminal epoxides gives -hydroxy acids which can be cyclized to ɑ-phenylthio--lactones. These can desulfurized with Raney nickel: J. Am. Chem. Soc., 108, 5352 (1986), or oxidatively, leading to butenolides: Chem. Lett., 385 (1974).

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GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2045072
Harmonized Tariff Code
2930.90
TSCA
No

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