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637-69-4 - 4-Methoxystyrene, 98%, stab. with 0.1% 4-tert-butylcatechol - 4-Vinylanisole - B22353 - Alfa Aesar

B22353 4-Methoxystyrene, 98%, stab. with 0.1% 4-tert-butylcatechol

CAS Number
637-69-4
Synonyms
4-Vinylanisole

Size Price ($) Quantity Availability
5g 47.48
25g 165.58
100g 583.78
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4-Methoxystyrene, 98%, stab. with 0.1% 4-tert-butylcatechol

MDL
MFCD00008619
EINECS
211-298-9

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Boiling Point
204-205°
Flash Point
72°(161°F)
Density
1.002
Refractive Index
1.5610
Solubility
Slightly miscible with methanol.

Applications

4-Methoxystyrene is employed in the ferric chloride-catalyzed addition of activated methylenes to styrenes. It acts as a monomer in polymerization reactions. Further, it is used to prepare 1,1,2,2-Tetracyano-3-(p-methoxyphenyl)cyclobutane by reacting with ethenetetracarbonitrile.

Notes

Light sensitive. Store in cool place. Incompatible with strong oxidizing agents and strong acids.

Literature References

Perkowski, A. J.; You, W.; Nicewicz, D. A. Visible Light Photoinitiated Metal-Free Living Cationic Polymerization of 4-Methoxystyrene. J. Am. Chem. Soc. 2015, 137 (24), 7580-7583.

Miyazawa, K.; Koike, T.; Akita, M. Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis. Chem. Eur. J. 2015, 21 (33), 11677-11680.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1098935
Harmonized Tariff Code
2909.30
TSCA
No

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