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Ethyl 5-bromothiophene-2-carboxylate is used as an intermediate in organic syntheses
Reuben D. Rieke.; Seung-Hoi Kim. 5-Bromo-2-pyridylzinc reagent; direct preparation and its coupling reactions. Tetrahedron Letters. 2011, 52, (2), 244-247.
Hye-Soo Jung.; Hyun-Hee Cho.; Seung-Hoi Kim. Site-selective mono-oxidative addition of active zinc into carbon-bromine bond of dibrominated-thiophenes: preparation of thienylzinc reagents and their applications. Tetrahedron Letters.2013, 54, (8), 960-964.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.