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B22436 2-Phenylpropionaldehyde, 97%

CAS Number
93-53-8
Synonyms
Hydratropaldehyde
2-Phenylpropanal

Stock No. Size Price ($) Quantity Availability
B22436-22 100g 41.90
B22436-36 500g 115.00
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2-Phenylpropionaldehyde, 97%

MDL
MFCD00006973
EINECS
202-255-5

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Boiling Point
92-94°/12mm
Flash Point
79°(174°F)
Density
1.010
Refractive Index
1.5170
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in most fixed oils, propylene glycol. Insoluble in glycerin.

Applications

2-phenylpropionaldehyde to give acetophenone using 1 atm molecular oxygen as oxidant was catalyzed by Ce(IV), V(IV) and Bronsted acids. It is used to produce 3-hydroxy-2-methyl-2-phenyl-propionaldehyde. This reaction will need reagent water and K2CO3.

Notes

Air Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Richard F. Heck. The palladium-catalyzed arylation of enol esters, ethers, and halides. A new synthesis of 2-aryl aldehydes and ketones. J. Am. Chem. Soc. 1968, 90, (20), 5535-5538.

Charles D. Thompson.; Michael T. Kinter.; Timothy L. Macdonald. Synthesis and in Vitro Reactivity of 3-Carbamoyl-2-phenylpropionaldehyde and 2-Phenylpropenal:? Putative Reactive Metabolites of Felbamate. Chem. Res. Toxicol.1996, 9, (8), 1225-1229.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H317-H319-H361f

Combustible liquid. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Suspected of damaging fertility.

Precautionary Statements: P201-P202-P210-P261-P264b-P272-P280-P281-P302+P352-P305+P351+P338-P308+P313-P333+P313-P337+P313-P362-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4291321
Harmonized Tariff Code
2912.29
TSCA
Yes
RTECS
CY1460000

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