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Bicyclo[3.2.0]hept-2-en-6-one is widely utilized to study enantioselective Baeyer-Villiger oxidation of (±)-cis-bicyclo(3.2.0)hept-2-en-6-one. It is used in the synthesis of a series of chalcone derivatives by reacting with arylaldehydes. It is also used to analyze the extremophile enzymes (monooxygenase and hydrolases) in microorganisms which are isolated from a deep-water petroleum reservoir and at high temperatures using fluorogenic assays and multibioreactions.
Butinar, L.; Mohorcic, M.; Deyris, V.; Duquesne, K.; Iacazio, G.; Bruno, M. C.; Friedrich, J.; Alphand, V. Prevalence and specificity of Baeyer-Villiger monooxygenases in fungi. Phytochemistry 2015, 177, 144-153.
Summers, B. D.; Omar, M.; Ronson, T. O.; Cartwright, J.; Lloyd, M.; Grogan, G. E. coli cells expressing the Baeyer-Villiger monooxygenase MO14 (ro03437) from Rhodococcus jostii RHA1 catalyse the gram-scale resolution of a bicyclic ketone in a fermentor. Org. Biomol. Chem. 2015, 13 (6), 1897-1903.
Hazard Statements: H226-H315-H319-H335
Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.