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B22481 Phosphorus(V) bromide, 95%

CAS Number
7789-69-7
Synonyms
Phosphorus pentabromide

Stock No. Size Price ($) Quantity Availability
B22481-14 25g 79.40
B22481-22 100g 212.00
B22481-36 500g 757.00
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Phosphorus(V) bromide, 95%

MDL
MFCD00011437
EINECS
232-186-6

Chemical Properties

Formula
PBr5
Formula Weight
430.50
Melting point
ca 105° dec.
Boiling Point
105-107° dec.
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

Phosphorus(V) bromide, is used in organic chemistry to convert carboxylic acids to acyl bromides

Notes

Moisture Sensitive. Keep container tightly closed. Store away from oxidizing agents.

Literature References

K.B. Dillon.; T.C. Waddington.; D. Younger. The characterization of the ions [PClnBr4-n]+ (0 ? n ? 4) in HCl solution. Inorganic and Nuclear Chemistry Letters. 1973, 9, (1), 63-67.

H. Donald Brooke Jenkins. Thermochemistry and energetics of the gaseous tetrabromophosphonium cation, PBr4+. Polyhedron. 1996, 15, (17), 2831-2834.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7350
Beilstein
3903332
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2812.90
TSCA
Yes

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