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2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.
Xue, X.; Yang, J.; Huang, W.; Yang, H.; Jiang, B. Synthesis of Hyperbranched Poly(epsilon-caprolactone) Containing Terminal Azobenzene Structure via Combined Ring-Opening Polymerization and Click Chemistry. Polymers 2015, 7 (7), 1248-1268.
Huang, X.; Zhang, N.; Ban, L.; Su, H. Synthesis of Star Poly(N-isopropylacrylamide) with a Core of Cucurbituril via ATRP and Controlled Thermoresponsivity. Macromol. Rapid Commun. 2015, 36 (3), 311-318.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.